Product ID:POLY BD R-45 HT RESIN
MSDS Date:11/20/1995
FSC:8030
NIIN:00N055584
MSDS Number: CFZLQ

ELF ATOCHEM

2000 MARKET STREET
PHILADELPHIA, PA 19103-3222
US

Emergency Phone: 610-582-1551;800-424-9300(CHEMTREC)

Info Phone: 800-328-2811

Cage: IO927

ELF ATOCHEM NORTH AMERICA INC

PHILADELPHIA, PA 19103-3222 US

Telephone: 800-245-5858

Cage: 86460

HYDROXY TERMINATED 1,3BUTADIENE HOMOPOLYMER

CAS: 69102-90-5

Fraction By Weight: 99.9%

OSHA PEL N/K

ACGIH TLV: N/K

<500

CAS: 100-40-3

RTECS: GW6650000

Fraction By Weight: <0.1%

ACGIH TLV: 0.1 PPM, A2; 9495

<5 PPM

CAS: 106-99-0

RTECS: EI9275000

Fraction By Weight: <0.1%

OSHA PEL 1000 PPM

ACGIH TLV: 2 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

OF VCH TO RATS & MICE BY INHAL (4 MOS) WAS RPTD TO

RTECS: 9999999ZZ

BLOOD CIRCULATION, WHILE RPTD ORAL DOSING (3 MOS) OF

RTECS: 9999999ZZ

OVARIAN EFTS IN FEMALE MICE @ DOSE THAT PRODUCED

RTECS: 9999999ZZ

STUDIES ON EFTS OF ORAL ADMIN OF VCH TO MALE &

RTECS: 9999999ZZ

FEMALE RATS & MALE MICE THAT NTP CONSIDERED THESE

RTECS: 9999999ZZ

TUMORS WAS OBSERVED IN FEMALE MICE. INCRD SENSIT OF

RTECS: 9999999ZZ

DEMONSTRATED BY THEIR ABILITY TO PRODUCE

RTECS: 9999999ZZ

VCH-1,2-EPOXIDE. NO EFTS WERE SEEN ON ABILITY OF

RTECS: 9999999ZZ

REDUCTIONS IN BODY WTS & NUMBERS OF GAMETES WERE

RTECS: 9999999ZZ

BACTERIAL CELLS.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE CONTACT: DIRECT CONTACT OR
VAPORS MAY CAUSE SLIGHT IRRITATION. SKIN CONTACT: LIQUID MAY CAUSE
SLIGHT IRRITATION. INGESTION: NO DATA CONCERNING ACUTE HEALTH
EFFECTS VIA INGESTION HAVE BEEN I DENTIFIED. INHALATION: NO DATA
CONCERNING ACUTE HEALTH EFFECTS VIA INHALATION HAVE BEEN
IDENTIFIED. (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS: NO EFTS FROM CHRONIC EXPOS KNOWN.
PROD CNTNS TRACE AMTS OF AN ODOROUS MATL IDENTIFIED AS
4-VINYLCYCLOHEXENE(VCH). UNDER AGGRESSIVE CNDTNS OF PHYS
HNDLG/W/HEATING, THERE IS POTNTL FOR RELS O F VCH AT CONCS NEAR
ACGIH THRESHOLD LIMIT VALUE OF 0.1 PPM. IN RUSSIAN WORKERS EXPOS TO
HIGH VCH CONCS (271-677 (SUPDAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYES: IMMED FLUSH W/FLOWING WATER FOR @ LST 15 MINS. SEE PHYS
IF IRRIT PERSISTS. SKIN: REMOVE CONTAM CLTHG & WASH EXPOSED SKIN
W/LGE AMTS OF WATER. SEE PHYS IF IRRIT PERSISTS. INGEST: NO HARMFUL
EFTS ANTIC IF POWDER IS SWALLOWED. SEE PHYS IF IRRIT PERSISTS.
INHAL: NO HARMFUL EFTS ANTIC FROM BRTHG LOW CONC OF VAPS. IF PROB
DEVELOPS, REMOVE PERS TO FRESH AIR AND SUPPLY OXYGEN IF NECESSARY.

Flash Point Method:OC
Flash Point:>400F,>204C
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . HAZARDOUS COMBUSTION PRODUCTS: SMALL QUANTITIES OF
BUTADIENE, ALONG WITH OXIDES OF CARBON.
Unusual Fire/Explosion Hazard:MOVE CNTNR FROM FIRE AREA IF POSS. COOL
FIRE EXPOS CNTNRS W/WATER WELL AFTER FIRE IS OUT TO PVNT POSS
EXPLO. HEAT FROM FIRE CAN GEN FLAM VAP THAT IS HVR/AIR.

Spill Release Procedures:VENTILATE AREA AND REMOVE ALL IGNITITION
SOURCES. CONTAIN SPILL BY BUILDING DIKE USING ABSORBENT MATERIAL.
COLLECT REMAINDER OF SPILL WITH ABSORBENT MATERIAL INTO A DRUM
APPROVED FOR WASTE DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MIN VAPOR BY SEALING IN TIGHTLY CLSD
CNTNR. STORE IN COOL, DRY, WELL-VENT AREA. KEEP AWAY FROM HEAT,
SPARKS, OPEN FLAMES & STRONG OXIDIZING AGENTS.
Other Precautions:PROTECT FROM FREEZING. IF FROZEN, THAW AND MIX
THOROUGHLY BEFORE USE. AVOID OVERHEATING. AVOID SKIN AND EYE
CONTACT.

Respiratory Protection:FOR CONDITIONS WHERE EXPOS TO DUST & FUMES IS
APPARENT, A NIOSH APPROVED RESPIRATOR FOR DUSTS, MISTS & FUMES
APPROP TO AIRBORNE CONC MAY BE WORN. WHERE VAPS ARE GEN, NIOSH
APPRVD ORG RESP SUITABLE TO AIRBORNE CONCS IS RECOMMENDED.
Ventilation:PROVIDE LOC EXHST VENT WHERE HEAT CAN CAUSE POLYMER
BREAKDOWN, E.G. EXTRUSION, MOLDING & WHERE THERE IS NEED TO
(SUPDAT)
Protective Gloves:NITRILE(NBR)/NATURAL RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR IMPERVIOUS BODY COVERING & BOOTS WHERE SPILLS OR SPLASHING
OCCUR.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT: DRAW DUSTS & FUMES FROM WORKER BRTHG ZONES. FOLLOWING PUBLICATION
OFFERS VENT GUIDELINES & TECHNIQUES: "INDUST VENT, A MANUAL OF
RECOM PRACTICE." AVAIL FROM ACGIH. EFTS OF OVEREXP: PPM), EYE & N
OSE IRRIT, HDCH, SOME WHITE BLOOD CELL REDUCTIONS & IMPAIRED
CARBOHYDRATE METABOLISM WERE REPORTED. RPTD ADMIN (ING 4)

Boiling Pt:B.P. Text:>572F,>300C
Spec Gravity:0.90
Evaporation Rate & Reference:NEGLIGIBLE (BUAC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
ACIDS AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, OPEN FLAME, PROLONGED STORAGE AT
ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON AND BUTADIENE.

Waste Disposal Methods:DISPOSE OF SOLID WASTE AT PROPERLY PERMITTED
LANDFILLS OBSERVING ALL LOCAL, STATE AND FEDERAL REGULATIONS.
CONTAMINATED LIQUIDS SHOULD BE CONCENTRATED & INCINERATED AT A
PROPERLY PERMITTED DISPOSAL SI TE AGAIN OBSERVING ALL LOCAL, STATE
& FED REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.